I would not care about such things if not for the prospect of obtaining Byakko's Haidate one day; with its 15 DEX, surely there must be some obvious increase in critical hit rate, right?
In fact, for some reason or another 15 DEX was once "thought" always to increase critical hit rate by a paltry 1-2% despite the reality of sampling error. (I've always wondered how people arrived at such conclusions by sampling. Even if you collected data through a parse, if you had a sample of 2500 hits, the margin of error associated with your crit rate estimate would be as much as 2%.) This conventional "wisdom" was then debunked around March 2007 with a discussion of the DEX/crit relation motivated by the observation that lots of DEX sent crit rates soaring up to some maximum. Coincidentally or not, around that time there was a parallel discussion on Allakhazam about the same topic.
Sure, these people didn't bother to control for mob AGI. Now, it appears evident that your DEX relative to your target's AGI is a factor in the critical hit rate determination. But for the experiments discussed in those threads, AGI wasn't controlled. The AGI of Robber Crabs, a test subject in the Alla thread, apparently is either 39 or 42, and the AGI of Tavnazian Sheep and Miner Bees, targets in the BG thread, probably varies too. But despite the lack of control it was obvious that piling on enough DEX will increase your critical hit rate markedly at some point.
Unfortunately, this conclusion is couched in the lazy terminology of "tiers." Some examples are
(1) "Stack enough DEX to break some critical rate tier, where each point of DEX you add within that tier has a larger effect."
(2) "Any large amounts of DEX before a critical rate tier will not have a major effect on critical hit rate."
Implicit in such statements is that if you don't break a "tier," it isn't worth trying to pile on DEX. In turn, considering that "tiers" in crafting refer to discontinuous jumps in HQ rate, it isn't surprising that a "tier" in terms of crit rate is also thought of as a sudden, discontinuous jump at some critical level of DEX. But the evidence provided in the above threads doesn't really point to such a discontinuous phenomenon.
First, consider the results from BG thread. Amazingly, the point estimates were given as approximations based on sample sizes of about 300 (really, that lazy not to record the exact sample sizes?), but that isn't that big a deal. But these point estimates are themselves random variables with corresponding distributions so it is helpful to visualize confidence intervals for the true values of these crit rates for given levels of DEX, and I created a graph to help with that:

The 95% confidence intervals are represented by black bars with the point estimates centered within the CIs. I also marked what are thought to be the minimum and maximum crit rates for DEX only with gray lines, 9% minimum and 24% maximum with 4/4 critical hit rate merits (who doesn't have those?). Critical hit rate bonuses from equipment are not subject to the caps.
The data corresponding to "low" and "high" DEX on this graph conform to the minimum and maximum crit rates. (At least there is no reason to believe otherwise.) At some point, though, crit rate increases with DEX in seemingly a linear fashion, which could awkwardly be described as a "tier," I suppose. This evokes a parallel with overall hit rate versus accuracy, with a minimum of 20% and a maximum of 95% and hit rate thought to vary linearly with accuracy in between. So if crit rate does increase (linearly) within a certain range of DEX, it is worth adding DEX within this interval all other things being equal. Sure, I guess you are within a "tier" when this happens, but where's the evidence for a discontinuous jump to reach this "tier"?
Furthermore, there is hardly any evidence for the plural tiers.
I've also graphed the first set of data from Allakhazam (first post), which is similar to the BG one:

Interestingly, here the crit rate estimates increase over a 15-DEX range, even more evidence against the idea of a discontinuous jump.
Finally, in the Alla discussion data from the Robber Crabs was pooled. Pooled data generally poses statistical hazards (for one, we're assuming the exact experimental conditions for each person involved but you figure there's gotta some idiot to fuck it up or some other factor... like the fact that the AGI of Robber Crabs varies!), but let's just run with this. I created a graph of 95% CIs for the pooled data as follows:
Even in violating statistical assumptions (independence) it is obvious there is no discontinuous jump in crit rate to be seen that cannot be attributed to sampling error. And even with the fundamental shadiness of this experiment (not controlling AGI), I even had the cheerful temerity to do least-squares linear regression (which itself is inappropriate for a variety of reasons) on the data points for which over 1000 samples were collected, in the DEX region where crit rate seems to increase linearly. For me it's enough to know that there is an obvious increase in crit rate; it doesn't matter what the exact increase will be for 1 additional DEX.
Also, the region is fairly narrow (10-15 DEX) for Robber Crabs, which would explain why people observe a sudden jump when adding DEX, as there is the view that adding DEX for the purposes of increasing crit rate should be an all-or-nothing thing (never mind the reality that the tradeoffs you make to stack DEX make such an attempt impractical).
It isn't necessarily true that the results from robber crabs can be generalized to other mobs. But if this phenomenon is real and can be generalized, then you may not have to go for an all-or-nothing attempt to increase crit rates with DEX, either in an auto-attack or WS phase, as long as your DEX is within the region where DEX is considered helpful.
For robber crabs, this region appears to be between 77 and 92 DEX. The higher level robber crabs in Kuftal Tunnel have 42 AGI, which jibes with the idea that your crit rate is capped when your DEX is 50 higher than your target's AGI.
The "transition region" clearly doesn't start when your DEX is equal to your target's AGI, but where should it start? The statement in the previous paragraph implies that it could start at about 35 DEX above your target's AGI, but this is a troublesome statement to make given that the crit rates consistently appear to be above 9% (the minimum) before 77 DEX. One possible explanation is that crit rate could be a minimum when (DEX - AGI) is less than or equal to 0, and rises very slowly from 0 to around 35. This could be why it's difficult to see any improvement in crit rates from adding DEX on your usual merit mobs, which all have AGI above 67.
I admit I didn't break any new ground, but I thought it might be fun to show my take on this.




